全文获取类型
收费全文 | 68190篇 |
免费 | 2787篇 |
国内免费 | 1245篇 |
专业分类
化学 | 33712篇 |
晶体学 | 998篇 |
力学 | 3832篇 |
综合类 | 93篇 |
数学 | 5829篇 |
物理学 | 27758篇 |
出版年
2022年 | 662篇 |
2021年 | 835篇 |
2020年 | 860篇 |
2019年 | 834篇 |
2018年 | 904篇 |
2017年 | 813篇 |
2016年 | 1395篇 |
2015年 | 1104篇 |
2014年 | 1517篇 |
2013年 | 3217篇 |
2012年 | 3219篇 |
2011年 | 3995篇 |
2010年 | 2732篇 |
2009年 | 2802篇 |
2008年 | 3358篇 |
2007年 | 3138篇 |
2006年 | 2945篇 |
2005年 | 2594篇 |
2004年 | 2307篇 |
2003年 | 2022篇 |
2002年 | 1885篇 |
2001年 | 3188篇 |
2000年 | 2347篇 |
1999年 | 1749篇 |
1998年 | 1283篇 |
1997年 | 1217篇 |
1996年 | 949篇 |
1995年 | 954篇 |
1994年 | 855篇 |
1993年 | 724篇 |
1992年 | 1035篇 |
1991年 | 1005篇 |
1990年 | 921篇 |
1989年 | 796篇 |
1988年 | 763篇 |
1987年 | 820篇 |
1986年 | 680篇 |
1985年 | 893篇 |
1984年 | 836篇 |
1983年 | 580篇 |
1982年 | 570篇 |
1981年 | 537篇 |
1980年 | 503篇 |
1979年 | 619篇 |
1978年 | 648篇 |
1977年 | 659篇 |
1976年 | 574篇 |
1975年 | 484篇 |
1974年 | 523篇 |
1973年 | 449篇 |
排序方式: 共有10000条查询结果,搜索用时 38 毫秒
101.
D. Amutha Rani Y. Yamamoto S. Mohri M. Sivakumar Y. Tsujita H. Yoshimizu 《Journal of Polymer Science.Polymer Physics》2003,41(3):269-273
In this study, a novel stepwise extraction method has been examined. The guest molecules housed between the helices of the clathrate δ form of syndiotactic polystyrene can be removed completely with this method. A systematic study of the preparation of a solvent‐free mesophase (emptied clathrate) membrane, its helical and residual solvent contents, and its structural transformations has been performed. In this first attempt, an enhancement in the TTGG helical content has been observed in the extracted membrane, and a conceptual mechanism is proposed. © 2002 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 269–273, 2003 相似文献
102.
A. Sanusi M. Z. A. Yahya S. Navaratnam W. J. Basirun Y. Alias N. S. Mohamed A. K. Arof 《Ionics》2003,9(3-4):253-257
In this study, lead sulphide (PbS) was prepared by the chemical bath deposition technique. The sample was characterized by
X-ray diffraction (XRD), Energy Dispersive Analysis of X-rays (EDAX) and cyclic voltammetry. EDAX spectrum shows peaks attributable
to lead and sulphur. The EDAX analysis also shows that the prepared sample is stoichiometric. Cyclic voltammetry experiments
were recorded at 100 mV·s−1 and 400 mV·s−1 scan rates. Results show that the rate controlling electrochemical reaction is electron transfer. The presence of redox waves
shows that the lithium intercalation and deintercalation can occur as a result of lattice expansion in PbS. There were no
differences in the PbS XRD data before and after the cyclic voltammetry experiments indicating that the PbS structure is not
modified upon lithium ion intercalation and deintercalation in PbS. The discharge characteristics for 35 cycles of the cell
using the LiCoO2/PbS couple is presented indicating the possible development of such materials as anode in lithium ion cells. 相似文献
103.
在程序升温条件下 ,用DSC研究了标题化合物的放热分解反应动力学 .用线性最小二乘法、迭代法以及二分法与最小二乘法相结合的方法 ,以积分方程、微分方程和放热速率方程拟合DSC数据 .在逻辑选择建立了微分和积分机理函数的最可几一般表达式后 ,用放热速率方程得到相应的表观活化能 (Ea)、指前因子 (A)和反应级数 (n)的值 .结果表明 :该反应的微分形式的经验动力学模式函数、Ea 和A值分别为 (1-α) 0 .44、2 30 .4kJ/mol和 10 18.16s-1.借助加热速率和所得动力学参数值 ,提出了标题化合物放热分解反应的动力学方程 .该化合物的热爆炸临界温度为 30 2 .6℃ .上述动力学参数对分析、评价标题化合物的稳定性和热变化规律十分有用 . 相似文献
104.
Haibo Peng Boyu Wu Qiong Song Fei Lu Shuyun Luo 《International Journal of Infrared and Millimeter Waves》2003,24(9):1587-1596
Hybrid electrode combined coplanar waveguide (CPW) and microstrip lines in ultra-broadband electro-optic modulators. The characteristics of the modulators with hybrid electrode is like that of the modulator with the microstrip lines, in which the microstrip electrode is loaded above only one arm of Mach-Zehnder (M-Z) optical waveguide, besides the problem of microstrip line to coaxial transition and corona polarization in polymer modulators have been best solved at the same time. By using finite element method (FEM), the characteristic parameters such as half-wave voltage, modulation bandwidth characteristic impedance, effective microwave refractive index of polymer modulators with microstrip line and hybrid electrode are analysed and compared in this paper. The results present that velocity match, impendence match and lower microwave propagating loss is easily realized in modulators with hybrid electrode. 相似文献
105.
D. Liu N.Q. Ngo X.Y. Dong S.C. Tjin P. Shum 《Applied physics. B, Lasers and optics》2005,81(6):807-811
We propose and experimentally demonstrate a stable dual-wavelength erbium-doped polarization-maintaining (PM) fiber laser
with tunable wavelength spacing using an all-PM linear cavity that makes use of two reflection peaks from the PM fiber Bragg
grating (PM-FBG). Experimental results show stable dual lasing lines with a wavelength separation of ∼0.22 nm and a large
optical signal-to-noise ratio (OSNR) of over 40 dB under room temperature. By applying axial strain to the PM-FBG, the center
wavelengths of the two lasing lines can be tuned over several nanometers and the wavelength separation between the lasing
lines can also be tuned to as small as 0.05 nm, which, to our knowledge, is the smallest wavelength spacing ever obtained
from a stable room-temperature dual-wavelength fiber laser. The proposed laser configuration has the advantages of simple
structure, low loss, stable dual-wavelength operation and a very small lasing linewidth of ∼5 kHz .
PACS 42.55.Wd; 42.81.-i; 42.81.Gs 相似文献
106.
J. Fujimoto T. Ishikawa M. Jimbo T. Kaneko T. Kon Y. Kurihara M. Kuroda Y. Shimizu Y. Yasui 《Pramana》2007,69(5):943-946
We report the recent development on the SUSY calculations with the help of GRACE system. GRACE/SUSY/1LOOP is the computer
code which can generate Feynman diagrams in the MSSM automatically and compute one-loop amplitudes in the numerical way. We
present new results of various two-body decay widths and chargino pair production at ILC (international linear collider) at
one-loop level.
相似文献
107.
Solid state nuclear track detectors are commonly used for measurements of concentrations of radon gas and/or radon progeny. All these measurements depend critically on the thickness of the removed layer during etching. However, the thickness of removed layer calculated using the etching period does not necessarily provide a sufficiently accurate measure of the thickness. For example, the bulk etch rate depends on the strength of stirring during etching for the LR 115 detector. We propose here to measure the thickness of the removed layer by using energy-dispersive X-ray fluorescence spectrometry. In the present work, a reference silver nitrate pellet is placed beneath the LR 115 detector, and the fluorescence X-ray intensity for silver is then measured. We have found a linear relationship between the X-ray intensity and the thickness of the removed layer for LR 115 detector. This provides a fast method to measure the thickness of removed layer from etching of LR 115 detector. However, this method was found to be inapplicable for the CR-39 detector. Therefore, alternative methods have yet to be explored for the CR-39 detector. 相似文献
108.
Liuman Ou Guilie Luo Yiping Li 《Journal of Mathematical Analysis and Applications》2003,283(2):534-548
In this paper, we consider an autonomous predator-prey Lotka-Volterra system in which individuals in the population may belong to one of two classes: the immatures and the matures, the age to maturity is represented by a time delay. By using eigenvalue analysis, principal term analyze method, reduction to absurdity, and iterative method, we obtain some simple conditions for global asymptotic stability of the unique positive equilibrium point. Moreover, a condition that the prey population in the system get extinction and the predator population in the system get permanence will be obtained. Meanwhile the theorems extend the corresponding conclusions in which there have no two stage structures. 相似文献
109.
Nickel complexes 1–4 ligated with 2,9-disubstituted-1,10-phenanthroline were synthesized and characterized by FT-IR spectra and elemental analysis.
The molecular structure of complex 2 was confirmed by X-ray crystal diffraction analysis. Activated with methylaluminoxane (MAO), those complexes showed moderate
activities for ethylene oligomerization.
Published in Kinetika i Kataliz, 2007, Vol. 48, No. 5, pp. 710–714.
This article was submitted by the authors in English. 相似文献
110.
J. Song H. Jiang Z.J. Liu D.Y. Khang Y. Huang J.A. Rogers C. Lu C.G. Koh 《International Journal of Solids and Structures》2008,45(10):3107-3121
A finite-deformation theory is developed to study the mechanics of thin buckled films on compliant substrates. Perturbation analysis is performed for this highly nonlinear system to obtain the analytical solution. The results agree well with experiments and finite element analysis in wavelength and amplitude. In particular, it is found that the wavelength depends on the strain. Based on the accurate wavelength and amplitude, the membrane and peak strains in thin films, and stretchability and compressibility of the system are also obtained analytically. 相似文献